IIRC from a decade or more ago, when I worked with aviation databases, the approach/departure frequencies were part of the airport record (we used the ARINC databases, and those were records which went along with each airport's set of records).
I don't recall how we got center frequencies, and we may not have, but certainly were able to list "Nearest" frequencies.
It's a nice feature, and even if it's not 100% accurate, the ability to try the first one or two on a list until you reach someone with an enroute request is pretty valuable.
Granted, I can get it from my 430W, but I'd second a motion to add these to the feature list in a future release.