So first, when you say "SkyView shows", are you talking about the fuel computer values or the actual SkyView fuel level readings? The per-tank fuel level values will show as accurate as your senders were calibrated, subject to not being able to read above where ever the sender tops out. So it's possible for you to have 15 gallon tanks, but if SkyView could only see 13 of that when you calibrated each tank, you'd see "13+" for the first few gallons when you're filled up.
But, the fuel computer adjustment will take any number you give it. The "MATCH" button is useful for synchronizing it to your tank sensors when you're mid-tank, although once your fuel flow sensor is well-calibrated this won't be necessary. The fuel computer also has the ability to remember "FULL" and "PRESET" values, so that when you fill-up, you can just tell the fuel computer so.
Real world example: My Sportsman has two 15 gallon main tanks, and two 10 gallon outboards that we usually don't fill but for long trips. When we fill up the mains, both quantity gauges say 13+, because the in-tank sensors can't see the last two gallons. After a trip to the fuel pump, SkyView will pipe-up that the computer doesn't match the in-tank sensors (because a bunch of fuel was just added). So our PRESET button sets the fuel computer to 30 gallons, which is just the mains filled. If I were going cross country, and filled everything, I'd press the FULL button, which sets the fuel computer to 50 gallons.
If, after landing and not refueling for some reason, I noticed that my in-tank sensors said said 10 and 7 gallons, but my fuel computer said 20 gallons (which is 3 gallons too many), I'd press the "MATCH" button to drag the fuel computer value to the measured quantity. Practically speaking, this doesn't happen in our airplane because our fuel flow is well-calibrated to the actual flow of the fuel that gets into the engine and turned into noise.